Past several years saw a great advance in low power digital and analog devices, allowing for longer lasting portable applications. Yet, selecting the optimal battery chemistry remains a daunting task. Primary (non-rechargeable) or secondary (rechargeable)? Coin cell, cylindrical or form fitted lithium-polymer? Each has its own benefits and drawbacks. Let’s take a quick look at them.
Cylindrical (AA, AAA) Primary Batteries
These are the batteries everyone recognizes and can pick up at just about any store with very little confusion. These are best if the end user needs to have the ability to easily and cheaply replace the power source. Typically these are alkaline batteries with a nominal voltage of ~1.5V, wherein lies the challenge: very few devices can run directly off of one alkaline battery, especially since it drains to ~0.9V. To enable single-cell use, a boost regulator would be necessary to provide the 3V or 5V rail. Even two batteries in series pose a challenge as they drain to a combined 1.8V, below the capability of many microcontrollers. So for a typical 3.3V to 5V application, three (2.7V-4.5V) or even four cells (3.6V-6V) in series might be required. Depending on the analog and digital components used, that might in turn require a buck regulator or an LDO for stable voltage or an even more complicated buck-boost regulator. So a consumer friendly power solution can become quite a quagmire of component selection, all along increasing the size of the device to a point where the battery cavity is probably dwarfing the rest of the components. Using AAA or even AAAA batteries instead of AA can yield significant weight and size gains at this level.
Another challenge in using alkaline batteries is the variation in capacity depending on the current draw. Going from 25 mA to 250 mA diminishes battery capacity by about 25% and having the batteries in series does not decrease the effect in anyway. One way to address that from end-user perspective is to use 1.5V Lithium primary batteries that provide virtually the same capacity regardless of the current draw. The downside to that solution is that the cost of the lithium batteries is 5 to 20 times more than alkaline batteries, pretty much eliminating the main benefit of having cylindrical primary batteries in the application from end user perspective. As the result, the consumers are more likely to use cheap alternative and complain about the application not lasting very long on battery power. Lithium batteries’ fast voltage drop also shortens the period of “almost discharged” time that consumers typically associate with AA/AAA batteries and observe through diminished brightness, slower motor, etc.
Finally, using more than one cylindrical battery in an application increases the chances of a consumer putting in cells of different chemistries or different discharge state, thus increasing the chances of malfunction or battery leakage.
Coin Cells (2032, etc.) Lithium Primary Batteries
The de facto batteries for low power and small volume applications, lithium coin cells come in a wide variety of sizes. Their voltage curve of 3V down to 2V makes them well suited for use with many electronic components and the small, flat size allows form factors that cylindrical batteries can only approximate with AAAA size. ‘2032’ coin cells are some of the most popular for consumer applications, but still fall in the category of “unusual” batteries as they are less common then AA/AAA batteries and considerably more expensive in general stores.
From application perspective, lithium coin cells have the same downside as alkaline in that their capacity greatly diminishes with increased current, but with even lower continuous current capability. In fact, using more than a few mA will have these batteries at a disadvantage to even a single alkaline with a boost regulator.
Photo Battery (primary), typically CR123
Based on the same chemistry as the coin batteries, CR123 photo batteries have the same electronics friendly discharge curve with increased capacity, continuous and peak current capabilities. While a single battery is a bit smaller than two AA or AAA batteries, the price to average consumer is considerably higher than alkaline batteries and on par with 1.5V Lithium batteries making it less consumer friendly.
Cylindrical (AA, AAA) Secondary Batteries
NiMh (Nickel Metal Hydride) and NiCd (Nickel Cadmium) are the main chemistries for these form factors with Low Self Discharge (LSD) NiMh reigning supreme for the past several years. With the nominal voltage of ~1.2V, these batteries have similar pros and cons as the primary alkaline batteries, somewhat higher continuous discharge currents and of course, the added benefit of recharging the batteries. The prices have been dropping in the past years and long term cost is extremely low
The problems of mixing different chemistries and charge conditions in multiple-cell applications remains and is complicated by the nominal voltage and internal resistance being different than those of alkaline and lithium batteries.
Li-ion Secondary Batteries
Lithium-ion rechargeable batteries have the distinction of coming in the widest variety of sizes as they can be created to fit just about any mold. This makes them popular for many space constrained applications like Bluetooth headsets. It also means that they are either non-user replaceable by design or expensive to replace.
By nature of being rechargeable, Li-ion battery will most likely need to include some sort of charging circuit in the application, complicating overall electronics design. Li-ion batteries have a 4.2V to ~2.7V discharge curve. This necessitates some sort of power conversion, be it an LDO, boost or buck-boost, for any application requiring a stable 3V/3.3V or 5V rail, adding yet another degree of complexity.
At last, shipping Li-ion batteries around the world is subject to many regulations, a potential additional cost that might not be taken into account when designing the product.
Mr. Fusion
Few improvements have been done to this technology since the ‘80s and the devices remain rather large, requiring special high power electronics, but providing nearly unlimited amount of power for DeLorean sized portable applications.